Ce:YAG Single Crystal — Scintillator & Phosphor Material Guide

Ce:YAG at a Glance
  • Material: Y₃Al₅O₁₂:Ce³⁺
  • Emission Peak: ~550 nm (green-yellow)
  • Decay Time: ~70 ns
  • Light Yield: ~20,000 photons/MeV
  • Typical Ce Doping: 0.1–0.2 at.%
  • Applications: X-ray imaging, radiation detectors, phosphors

Ce:YAG (Cerium-doped Yttrium Aluminum Garnet) is a widely used scintillator and phosphor crystal known for its fast decay time, high mechanical strength, and excellent optical stability. With strong green-yellow emission around 550 nm under X-ray, gamma-ray, or electron excitation, Ce:YAG is commonly used in radiation detection, X-ray imaging screens, electron microscopy, and optical readout systems.

The scintillation performance of Ce:YAG depends strongly on Ce³⁺ doping concentration, crystal quality, polishing, and optical coupling. This guide explains how Ce:YAG crystals are grown, how doping affects light yield and decay time, what specifications are required for detector-grade crystals, and how to order custom Ce:YAG components for scientific and industrial applications.

SECTION A — Growth Method for Ce:YAG Crystals

✔ Czochralski (CZ) Growth

Ce:YAG single crystals are typically grown using the Czochralski method, which provides:

  • High optical clarity
  • Uniform Ce³⁺ distribution
  • Large crystal sizes
  • Low defect density
  • Excellent mechanical robustness

✔ Valence Control (Ce³⁺ Stability)

Cerium must remain in the Ce³⁺ state for efficient scintillation. Growth atmosphere and post-annealing are carefully controlled to suppress Ce⁴⁺ formation.

SECTION B — Ce³⁺ Doping Concentration & Scintillation Properties

Typical Ce doping levels

Application Ce Concentration
X-ray imaging screens 0.05–0.2 at.% Ce
Scintillation detectors 0.1–0.5 at.% Ce
Phosphor converters 0.1–0.3 at.% Ce

Why doping matters

  • Higher Ce → stronger absorption & emission
  • Excessive Ce → concentration quenching
  • Optimal Ce improves light yield & decay speed

Most detector-grade Ce:YAG uses 0.1–0.2 at.% Ce.

SECTION C — Scintillation Characteristics of Ce:YAG

  • Emission peak: ~550 nm
  • Decay time: ~70 ns
  • Light yield: ~20,000 photons/MeV
  • Radiation hardness: High
  • Afterglow: Very low

These properties make Ce:YAG suitable for fast imaging and high-rate radiation detection.

SECTION D — Optical Polishing & Surface Preparation

Ce:YAG is mechanically hard (Mohs ~8.5) and supports high-quality polishing.

  • Scratch–dig: 40–20 (standard) or 20–10 (imaging-grade)
  • Flatness: λ/4 to λ/10 @ 632 nm
  • Surface roughness: Ra < 5–10 nm

Common forms include polished plates, thin scintillator screens, and detector blocks.

SECTION E — Optical Coupling & Coatings

  • CCD / CMOS sensors
  • Photodiodes
  • PMTs / SiPMs
  • Single- or double-side optical polishing
  • AR coating @ 550 nm (optional)
  • Diffuse back surface (imaging screens)
  • Optical epoxy or grease coupling

SECTION F — Applications of Ce:YAG Crystals

✔ Radiation Detection

  • X-ray detectors
  • Gamma-ray imaging
  • Electron beam detection

✔ Imaging & Microscopy

  • X-ray imaging screens
  • SEM / TEM scintillator screens
  • Scientific cameras

✔ Phosphor & Light Conversion

  • White LED phosphors
  • Laser-pumped phosphor sources

✔ Scientific Instrumentation

  • X-ray residual stress analyzers
  • Synchrotron diagnostics
  • LIBS / optical detection systems

Recommended Ce:YAG Products & Custom Solutions

Based on the specifications above, the following Ce:YAG single crystal products are commonly used in scintillator and phosphor applications. Custom dimensions, doping levels, surface finishes, and optical coupling solutions are available upon request.

SECTION H — How to Order a Custom Ce:YAG Scintillator

  • Ce³⁺ concentration (0.05–0.5 at.%)
  • Crystal dimensions & thickness
  • Surface finish (polished / diffused)
  • Optical coupling method
  • Coating requirements (AR @ 550 nm)
  • Application type

Design-Realized also provides detector assemblies, optical coupling fixtures, and small-batch scintillator prototyping.

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